Matt Dawber's group in the Department of Physics and Astronomy at Stony Brook University is focused on the growth, characterization and understanding of ferroelectric materials and other oxides. Besides a general interest in ferroelectric materials the focus in this lab is on producing superlattice materials where interfacial coupling gives rise to either enhanced or totally new behaviour. Ferroelectric materials possess high degrees of functionality making them extremely useful in a broad variety of applications. Find out more on our research overview page.
From Left to Right
Back Row: Mohammed Yusuf, Kevin Chen, John Sinsheimer, Benjamin Bein, Matt Dawber
Front Row: Sara Callori, Juli Coraor, Grace Pan
Absent: Lukas Kuerten
In-situ x-ray diffraction study of the growth of highly strained epitaxial BaTiO3 thin films
J. Sinsheimer, S. J. Callori, B. Ziegler, B. Bein, P. V. Chinta, A. Ashrafi, R. L. Headrick and M. Dawber
In-situ synchrotron x-ray diffraction was performed during the growth of BaTiO3 thin films on SrTiO3 substrates using both off-axis RF magnetron sputtering and pulsed laser deposition techniques. It was found that the films were ferroelectric during the growth process, and the presence or absence of a bottom SrRuO3 electrode played an important role in the growth of the films. Pulsed laser deposited films on SrRuO3 displayed an anomalously high tetragonality and unit volume, which may be connected to the previously predicted negative pressure phase of BaTiO3.
Engineering polarization rotation in a ferroelectric superlattice
J. Sinsheimer, S.J. Callori, B. Bein, Y. Benkara, J. Daley, J. Coraor, D. Su, P.W. Stephens, and M. Dawber
A key property that drives research in ferroelectric perovskite oxides is their strong piezoelectric response in which an electric field is induced by an applied strain, and vice-versa for the converse piezoelectric effect. We have achieved an experimental enhancement of the piezoelectric response and dielectric tunability in artificially layered epitaxial PbTiO3/CaTiO3 superlattices through an engineered rotation of the polarization direction. As the relative layer thicknesses within the superlattice were changed from sample to sample we found evidence for polarization rotation in multiple x-ray diffraction measurements. Associated changes in functional properties were seen in electrical measurements and piezoforce microscopy. The results demonstrate a new approach to inducing polarization rotation under ambient conditions in an artificially layered thin film.
This paper is also available on the arXiv at http://arxiv.org/abs/1209.3227.
Ferroelectric PbTiO3/SrRuO3 superlattices with broken inversion symmetry
S.J. Callori, J. Gabel, D. Su, J. Sinsheimer, M.V. Fernandez-Serra, M. Dawber
We have fabricated PbTiO3/SrRuO3 superlattices with ultra-thin SrRuO3 layers. Due to the superlattice geometry, the samples show a large anisotropy in their electrical resistivity, which can be controlled by changing the thickness of the PbTiO3 layers. Therefore, along the ferroelectric direction, SrRuO3 layers can act as dielectric, rather than metallic, elements. We show that, by reducing the concentration of PbTiO3, an increasingly important effect of polarization asymmetry due to compositional inversion symmetry breaking occurs. The results are significant as they represent a new class of ferroelectric superlattices, with a rich and complex phase diagram. By expanding our set of materials we are able to introduce new behaviors that can only occur when one of the materials is not a perovskite titanate. Here, compositional inversion symmetry breaking in bi-color superlattices, due to the combined variation of A and B site ions within the superlattice, is demonstrated using a combination of experimental measurements and first principles density functional theory.
This paper is also available on the arXiv at http://arxiv.org/abs/1201.2893
Research in our lab is supported by the National Science Foundation under: