Matt Dawber's group in the Department of Physics and Astronomy at Stony Brook University is focused on the growth, characterization and understanding of ferroelectric materials and other oxides. Besides a general interest in ferroelectric materials the focus in this lab is on producing superlattice materials where interfacial coupling gives rise to either enhanced or totally new behaviour. Ferroelectric materials possess high degrees of functionality making them extremely useful in a broad variety of applications. Find out more on our research overview page.
Ferroelectric PbTiO3/SrRuO3 superlattices with broken inversion symmetry
S.J. Callori, J. Gabel, D. Su, J. Sinsheimer, M.V. Fernandez-Serra, M. Dawber
We have fabricated PbTiO3/SrRuO3 superlattices with ultra-thin SrRuO3 layers which act as dielectric, rather than metallic, elements. The superlattices display both ferroelectricity and, as the volume fraction of PbTiO3 is reduced, an increasingly important effect of polarization asymmetry due to compositional inversion symmetry breaking. The results are significant as they represent a new class of ferroelectric superlattices. By expanding our set of materials we are able to introduce new behaviors that can only occur when one of the materials is not a perovskite titanate. Here, compositional inversion symmetry breaking in bi-color superlattices, due to the combined variation of A and B site ions within the superlattice, is demonstrated using a combination of experimental measurements and first principles density functional theory.
A preprint of this paper is available on the arXiv at http://arxiv.org/abs/1201.2893
Research in our lab is supported by the National Science Foundation under: